We calculate the Lambda_c\bar{\Lambda}_c$ partial decay width of the excited vector charmonium states around 4.6 GeV with the quark pair creation model. We find that the partial decay width of the $\Lambda_c\bar{\Lambda}_c$ mode can reach up to several MeV for $\psi(4S,~5S,~6S)$. In contrast, the partial $\Lambda_c\bar{\Lambda}_c$decay width of the states $\psi(3D,~4D,~5D)$ is less than one MeV. If the enhancement $Y(4630)$ reported by the Belle Collaboration in $\Lambda_c\bar{\Lambda}_c$ invariant-mass distribution is the same structure as $Y(4660)$, the $Y(4660)$ resonance is most likely to be a $S$-wave charmonium state.