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Removal of hydrogen sulfide in carbon dioxide for radiocarbon AMS analysis

SPT-2
24 Oct 2024, 09:40
20m
GRAND BALLROOM (宴会厅), 2nd Floor

GRAND BALLROOM (宴会厅), 2nd Floor

GULIN BRAVO HOTEL (桂林宾馆),14 Ronghu Road, Guilin, 541002, China
Oral Presentation Sample Preparation Techniques Sample Preparation Techniques

Speaker

Dr Mark Roberts (Woods Hole Oceanographic Institution)

Description

A method of hydrogen sulfide removal in water (for DIC radiocarbon analysis) or carbon dioxide gas was investigated. By using a silver nitrate solution in diluted nitric acid in a gas wash device, or a trap filled with silver nitrate impregnated silica gel, the hydrogen sulfide was easily removed from the carbon dioxide. The cleaned CO2 is pure enough to get reduced by hydrogen on the iron catalyst for graphite AMS measurement. The blank of this clean-up method is negligible. It will not change the isotopic composition of the CO2. This method is applied to some hydrogen sulfide containing samples successfully.

Student Submission No

Primary author

Dr Li Xu (Woods Hole Oceanographic Institution)

Co-authors

Mr Alan Gagnon Dr Mark Roberts (Woods Hole Oceanographic Institution) Dr Roberta Hansman (Woods Hole Oceanographic Institution) Mrs Kathern Elder (Woods Hole Oceanographic Institution) Dr Jeffrey Seewald (Woods Hole Oceanographic Institution) Dr Susan Lang (Woods Hole Oceanographic Institution)

Presentation materials

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