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Rapid UV-Oxidation setup at ETH for AMS radiocarbon analysis of dissolved organic carbon in marine and freshwater samples

PSA-51
21 Oct 2024, 17:15
20m
Lobby and Hallway , 2nd Floor (( Poster session A should be set up in the morning.))

Lobby and Hallway , 2nd Floor

( Poster session A should be set up in the morning.)

Poster Small C-14 Sample Techniques and Applications Poster Session A

Speaker

Dr Negar Haghipour (1Geological Institute, Department of Earth Sciences, ETH Zurich, 8092 Zurich, Switzerland 2 Laboratory for Ion Beam Physics, ETH Zürich, Switzerland)

Description

Dissolved organic carbon (DOC) is a major, yet little understood component of the global carbon cycle. Although radiocarbon analysis of DOC provides valuable information on the origin and age of this pool, the number of measurements, particularly in marine systems, is limited by the complexity and low efficiency of existing methods. These methods generally use UV irradiation to oxidize the organic carbon, and then perform 14C analyses on the resulting CO2. Disadvantages of most currently applied UVox methods include being limited to the processing of only one sample at a time, the large sample volumes required, and relatively high processing blanks. Here, we present a compact UV-Oxidation system, where up to 12 water samples can be oxidized simultaneously in separate quartz reactors arranged around a single UV lamp. This simple setup uses helium instead of vacuum to speed up the extraction of the CO2 formed after oxidation. Key improvements of the new UVox setup include: 1) Reduced required sample volumes (30- 60 ml instead of 1L), as samples are measured for 14C with the Micadas gas ion source, 2) High UV oxidation efficiency for standards (96%), 3) No KI trap needed, 4) Decreased processing time with the possibility of oxidizing up to 12 samples in 4-6 h, 5) And the possibility of combining CO2 from different reactors to one trap, enabling the measurement of samples with very low DOC concentrations. We determined a low background of 2.3 ± 0.6 µgC with F14C= 0.27±0.05 on fossil and modern standards dissolved in pre-irradiated Milli-Q water. We will present the reproducibility of the line and first measurements on DOC samples from Swiss lakes and the Sargasso Sea.

Student Submission No

Primary author

Dr Negar Haghipour (1Geological Institute, Department of Earth Sciences, ETH Zurich, 8092 Zurich, Switzerland 2 Laboratory for Ion Beam Physics, ETH Zürich, Switzerland)

Co-authors

Dr Maarten Lupker (1Geological Institute, Department of Earth Sciences, ETH Zurich, 8092 Zurich, Switzerland) Dr Lukas Wacker ( 2 Laboratory for Ion Beam Physics, ETH Zürich, Switzerland) Dr Margot White (1Geological Institute, Department of Earth Sciences, ETH Zurich, 8092 Zurich, Switzerland) Mrs Charlotte Schnepper (1Geological Institute, Department of Earth Sciences, ETH Zurich, 8092 Zurich, Switzerland) Prof. Tim.I. Eglinton (1Geological Institute, Department of Earth Sciences, ETH Zurich, 8092 Zurich, Switzerland)

Presentation materials

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